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DIVISION S-5—PEDOLOGY

Pedogenesis of Volcanic Ash Soils in Andean Ecuador

Dep. of Crop and Soil Sciences, Univ. of Georgia, Athens, GA 30602

^* Corresponding author (wmiller{at}uga.edu).

Weathering and development of volcanic ash soils show similar patterns in different regions of the world; however, the specific environmental conditions at a given location result in a unique combination of factors and processes governing soil formation. This research was conducted to study pedogenesis on volcanic slopes in the inter-Andean valley of northern Ecuador. Twelve pedons representing different pedogenic environments were sampled at elevations between 2410 and 4050 m above sea level (asl). In pedons above 3200 m asl, allophane and Al–humus complexes dominate the colloidal fraction, the topsoils are high in organic matter, and the soils classify as Andisols with melanic epipedons. In pedons below 2700 m asl, halloysite is the predominant colloidal constituent, the topsoils contain <1% organic C, and the soils are Inceptisols and Entisols. The pedons at intermediate elevations mark a transition zone, in which allophane and halloysite coexist and the soils generally classify as Andisols with umbric epipedons. This general altitudinal pattern was found to be altered in unstable landscape positions, where andic soil properties have been removed along with the erosion of topsoil material. Virtually the same altitudinal weathering sequence was observed in the 3000-yr-old soils and in buried paleosols, which are considered to be older than 40 000 years. Thus, different time of pedogenesis has not caused marked differences in the composition of the colloidal fraction. Climate is considered the overriding factor responsible for the observed altitudinal differences in soil development by affecting leaching regime and organic matter decomposition.

Abbreviations: Al_p, pyrophosphate-extractable Al • asl, above sea level • BP, before present • DSC, differential scanning calorimetry • EG, ethylene glycol • ET, evapotranspiration • IR, infrared spectroscopy • subscript [o], acid oxalate-extractable • XRD, X-ray diffraction

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