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Fig. 1. Conceptual representation of the structure in the ith particle-size fraction, assembled in the form of a cube: (a) natural state of packing, (b) cubic, close-packed, consisting of uniform-size spherical particles, and (c) an enlarged subsection of the cross-sectional area of (b). The value of Li(c) in (b) can be estimated as follows: bulk volume of the assemblage = (2Rini1/3)3 = 8Ri3ni; solid volume of ni particles = (4 Ri3ni)/3; pore volume in assemblage = 8Ri3ni – (4 Ri3ni)/3; Area ABCD = 4Ri2; area (a + b + c + d) = 4(0.25 Ri2) = Ri2; cross-sectional area of a single pore = 0.858Ri2. Therefore, if the total pore volume is represented by a single cylindrical pore, the total pore length, Li(c) is 3.811Ri3ni/0.858Ri2 = 4.44Rini. For variable definitions, see the Appendix.
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