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Soil Organic Matter Clogs Mineral Pores

Evidence from 1H-NMR and N2 Adsorption

Christian Mikutta*, Friederike Lang and Martin Kaupenjohann

Dep. of Soil Science, Institute of Ecology, Berlin Univ. of Technology, Salzufer 11-12, D-10587 Berlin, Germany



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Fig. 1. X-ray diffractograms of pure PGA- and DOM-coated AlOOH.

 


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Fig. 2. Environmental scanning electron micrographs of (a) uncoated AlOOH at 100 Pa, (b) PGA-coated AlOOH at 100 Pa, and scanning electron micrographs of (c) freeze-dried AlOOH, and (d) freeze-dried DOM-coated AlOOH.

 


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Fig. 3. Nitrogen adsorption and desorption isotherms of freeze-dried pure, DOM-, and PGA-treated AlOOH samples.

 


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Fig. 4. Cumulative pore-size distribution of surface area (SSABET) and pore volume of DOM + reference (a,c), and PGA + reference (b,d). The insets give the cumulative pore-size distribution of pores <5 nm. Error bars represent standard deviation.

 


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Fig. 5. (a) T2 relaxation time constant distribution f(T2) of pure and PGA-treated AlOOH, and (b) calculated pore-size distribution f(P) of pure and PGA-treated AlOOH.

 





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