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Characterization of Soil Organic Matter Fractions of Tundra Soils in Arctic Alaska by Carbon-13 Nuclear Magnetic Resonance Spectroscopy

X.Y. Daia, C.L. Pinga, R. Candlera, L. Haumaierb and W. Zechb

a Agricultural and Forestry Experiment Station, Univ. of Alaska, 533 E. Fireweed, Palmer, AK 99645 USA
b Institute of Soil Science and Soil Geography, Univ. of Bayreuth, 99440 Bayreuth, Germany



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Fig. 1. Liquid-state 13C nuclear magnetic resonance (NMR) spectra of HA, FA, LMA, HON, and LMN derived from alkali extracts of the Oa1 horizon in Site 1 soil. HA, humic acids (14700 scans); FA, fulvic acids (13801 scans); LMA, low-molecular-weight acids (17000 scans); HON, hydrophobic neutrals (14001 scans); LMN, low-molecular-weight neutrals (14220 scans)

 


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Fig. 2. Liquid-state 13C nuclear magnetic resonance (NMR) spectra of HA, FA, and LMA derived from alkali extracts of the Oa2 horizon in Site 1 soil. HA, humic acids (16710 scans); FA, fulvic acids (14001 scans); LMA, low-molecular-weight acids (13760 scans)

 


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Fig. 3. Cross-polarization, magic angle spinning (CPMAS) 13C nuclear magnetic resonance (NMR) spectra of the whole soils from Site 1 (Oa1 and Oa2 horizons), Site 2 (Oe and O/A horizons), and Site 3 (Cf horizons) 8829 and 13499 scans for the Site 1 soil Oa1 and Oa2 horizons, respectively; 15353 and 55168 scans for the Site 2 soil Oe and O/A horizons, respectively; and 115534 scans for the Site 3 soil Cf horizon

 


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Fig. 4. Cross-polarization, magic angle spinning (CPMAS) 13C nuclear magnetic resonance (NMR) spectra of the humin fractions from Site 1 soil (Oa1 and Oa2 horizons), Site 2 soil (Oe and O/A horizons), and Site 3 soil (Cf horizon). 150917 and 61612 scans for the Site 1 soil Oa1 and Oa2 horizons, respectively; 18825 and 80194 scans for the Site 2 Soil Oe and O/A horizons, respectively; and 199912 scans for the Site 3 Cf horizon

 





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