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Rheological Properties of Aqueous Suspensions of Palygorskite

Alexander Neamana and Arieh Singera

a The Seagram Center for Soil and Water Sciences, The Faculty of Agricultural, Food and Environmental Quality Sciences, The Hebrew University of Jerusalem, Rehovot 76100, Israel



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Fig. 1 Flow curves of 3% (w/v) suspensions of Na–palygorskites at pH 7

 


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Fig. 2 Transmission electron micrographs of the (a) Yucatan and (b) Mt. Flinders samples

 


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Fig. 3 Effect of fiber ellipticity on (a) plastic viscosity, (b) Bingham yield value, and (c) apparent viscosity of 3% (w/v) suspensions at pH 7 for Na–palygorskites used in the study

 


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Fig. 4 Flow curves of Na–palygorskite from the Negev at different suspension concentrations at pH 7

 


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Fig. 5 Plastic viscosity of Na–palygorskite suspensions at pH 7 as a function of suspension concentration

 


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Fig. 6 Flow curves of 5% (w/v) suspensions of Yucatan palygorskite adsorbed with different ions at pH 7

 


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Fig. 7 Relationship between pH and electrophoretic mobility at different electrolyte concentrations for Na–palygorskite from the Negev

 


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Fig. 8 Scanning electron micrographs of Na–palygorskite from the Negev showing differences in arrangement of fibers in suspension between low and high pH values: (a, b) pH 3 at different magnifications and (c, d) pH 10 at different magnifications

 


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Fig. 9 Flow curves of 3% (w/v) suspensions of Na–palygorskite from the Negev at different pH values

 


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Fig. 10 The effect of electrolyte addition on (a) plastic viscosity and (b) Bingham yield value of 3% (w/v) suspensions at different pH values for Na–palygorskite from the Negev

 


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Fig. 11 Flow curves of 3 and 5% suspensions of Na–palygorskite from Florida at pH 7 showing antithixotropic behavior of the suspensions

 


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Fig. 12 The effect of pH on hysteresis loop area enclosed by flow curves of 3% suspensions of Na–palygorskite from Florida at different electrolyte concentrations. The area of hysteresis loop is accepted to be positive if the behavior of the system is thixotropic and negative if the behavior is antithixotropic

 





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