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Response of the Osmotic Tensiometer to Varying Temperatures

Modeling and Experimental Validation

P.Maarten Biesheuvela, Ron Raangsb and Henk Verweija

a Lab. for Inorganic Materials Sci., Dep. of Chem. Technol. and MESA Res. Inst., Univ. of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands
b Dep. of Environ. Sci., Subdep. Water Resour., Wageningen Univ., Nieuwe Kanaal 11, 6709 PA Wageningen, The Netherlands



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Fig. 1 Construction of osmotic tensiometer: 1, ceramic filter; 2, injection point; 3, brass housing; 4, cell filled with polymer–water solution; 5 pressure transducer; 6, data transfer

 


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Fig. 2 Dimensions of typical tensiometer cup

 


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Fig. 3 Pressure transducer (a) without pressure difference and (b) flexed due to pressure difference

 


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Fig. 4 Experiment (dots) vs. model (solid line) for an osmotic tensiometer submersed in free water for 3 d. Model and measurements start at T = 24°C and P = 1.24 MPa and they make three loops in clockwise direction. The dashed line gives the absolute value of the osmotic potential

 


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Fig. 5 Parity plot showing the agreement between the model and the experiments of Fig. 4

 


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Fig. 6 Influence of the group SK on the pressure response curves for the osmotic tensiometer. The absolute value of the osmotic potential |{psi}o| is a straight line starting at T = 12°C and P = 1.4 MPa with a gradient of -ß = 3.75 x 104 Pa K-1

 





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