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a Dep. de Suelo y Agua, Estación Experimental de Aula Dei, Consejo Superior de Investigaciones Científicas, P.O. Box 13034, 50080, Zaragoza, Spain
b Dep. de Física de la Materia Condensada, Instituto de Ciencia de Materiales de Aragón, Consejo Superior de Investigaciones Científicas, Univ. de Zaragoza, C/Pedro Cerbuna 12, 50009, Zaragoza, Spain
c Dep. de Ingeniería Electrónica y Comunicaciones, Instituto de Ciencia de Materiales de Aragón, Consejo Superior de Investigaciones Científicas, Univ. de Zaragoza, C/María de Luna 1, 50018, Zaragoza, Spain
* Corresponding author (david@eead.csic.es).
Time domain reflectometry (TDR) is a technique that allows simultaneous estimates of apparent permittivity (
a) and hence volumetric water content (
) and bulk electrical conductivity (
a). Difficulties arise for
and
a determination, however, when uncoated TDR probes (UP) are used in highly conductive media. This work shows that
a can be estimated in highly conductive media using a TDR probe coated with a high-dielectric insulator (CP). To this end, the Dalton method for
a estimations was applied to a 10-cm-long three-rod TDR probe insulated with a 0.2-mm-thick epoxy-ceramic composite coating with a relative permittivity,
r, of 32.3. This method was calibrated on different NaCl–water solutions (0–15 dS m–1) and compared with the standard long-time TDR method for
a estimations using an UP. The method was subsequently used for determining
a in four different soils with different values of
and
a (0–6 dS m–1) and again compared with the standard TDR procedure. The low error (RMSE = 1.5) for the comparison between the
a measured with the CP and that calculated with the analytical solution for coaxial probes indicates that the CP is accurate enough for
a estimations. For
a values <4 dS m–1, the UP allows determinations of
a and the most accurate estimations of
a using the standard TDR method (R2 = 0.99). For higher
a values, however, estimations of
a were only possible using the CP, where
a was satisfactorily determined (R2 = 0.99) using the Dalton method. To this end, a previous calibration between the real and the apparent bulk electrical conductivity estimated with the CP was required.
Abbreviations: CP, high-dielectric coated time domain reflectometry probe DC, direct current TDR, time domain reflectometry UP, uncoated time domain reflectometry probe
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