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Institute for Biodiversity and Ecosystem Dynamics (IBED), Earth Surface Processes and Materials (ESPM), Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, the Netherlands
* Corresponding author (k.g.j.nierop{at}science.uva.nl).
The volcanic ash soils along an altitudinal transect in Guandera Biological Station in northern Ecuador have been developed under varying vegetation around the upper forest line. Generally, the soils currently covered by forest are composed of Fulvic Andosols (melanic index >1.7) while those under páramo (tropical alpine grasslands) have developed into Melanic Andosols. This vegetation effect on soil formation is believed to be associated with differences in organic matter composition. In this study, we examined whether Fulvic Andosols differed from Melanic Andosols in organic matter composition. Using analytical pyrolysis techniques, we found hardly any differences in the organic matter characteristics related to vegetation cover, not even between soils that supposedly have been covered by forest and páramo for millennia. Small differences were found within the lipid compounds, while the polysaccharides and lignin were virtually absent from the (deeper) mineral soil horizons. The low abundance of polysaccharides in soils that have undergone severe organic matter decomposition is not unusual for most soils, but is uncommon in other Andosols studied with the same pyrolysis techniques.
Abbreviations: OM, organic matter SOM, soil organic matter THM, thermally assisted hydrolysis and methylation UFL, upper forest line
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