HOME HELP FEEDBACK SUBSCRIPTIONS ARCHIVE SEARCH TABLE OF CONTENTS		QUICK SEARCH:   [advanced] Author: Keyword(s): Year:  Vol:  Page:

This Article Figures Only Full Text Full Text (PDF) Alert me when this article is cited Alert me if a correction is posted Services Similar articles in this journal Similar articles in ISI Web of Science Alert me to new issues of the journal Download to citation manager Citing Articles Citing Articles via ISI Web of Science (5) Citing Articles via Google Scholar Google Scholar Articles by Mashal, K. Articles by Flury, M. Search for Related Content PubMed Articles by Mashal, K. Articles by Flury, M. GeoRef GeoRef Citation Agricola Articles by Mashal, K. Articles by Flury, M. Related Collections Fate Colloids Industrial Wastes Mixed Wastes Soil Surface Chemistry

Division S-9—Soil Mineralogy

Clay Mineralogical Transformations over Time in Hanford Sediments Reacted with Simulated Tank Waste

Dep. of Crop and Soil Sciences, Center for Multiphase Environmental Research, Washington State Univ., Pullman, WA 99164-6420

^* Corresponding author (flury{at}mail.wsu.edu)

Buried waste storage tanks at the USDOE Hanford Reservation in Washington State have released solutions containing high concentrations of Na, OH, NO₃, and Al into the vadose zone. When such solutions contact vadose zone sediments, mineral transformations will change the sediment matrix. We hypothesized that Si, dissolved from primary and secondary minerals, will combine with Al from the tank waste to form crystalline or poorly crystalline network silicates such as zeolites and feldspathoids. In this study, we characterized the colloidal (<2 µm equivalent diam.) minerals formed when simulated tank solutions reacted with vadose zone Hanford sediments. Variables studied included simulated tank waste (STW) composition, reaction time, and temperature. Hanford sediments were reacted with a series of simulated tank solutions in batch experiments at 25 and 50°C for 1, 10, 25, 40, and 50 d. The mineralogical, structural, and chemical properties of the resulting colloidal fractions and bulk solutions were determined by x-ray diffraction (XRD), Fourier transform infrared (FTIR), ²⁷Al- and ²⁹Si-magic angle spinning-nuclear magnetic resonance (MAS-NMR), scanning electron microscopy (SEM), energy-dispersive x-ray analysis (EDAX), colorimetry, atomic absorption spectroscopy, and inductively coupled plasma–atomic emission spectroscopy (ICP–AES). Upon contact with STW, Si was released from the sediments and a portion was incorporated into poorly crystalline solids. The amount of poorly crystalline solids increased initially and reached maximum quantities between 0 and 25 d. Lability of minerals in the presence of NaOH followed the order quartz kaolinite illite. New secondary minerals, NO₃–cancrinite, NO₃–sodalite, and zeolite A, were formed at the expense of the original clay minerals. Zeolite A was labile and disappeared after about 25 d of reaction time. Cancrinite and sodalite, however, appeared to be stable and increased in abundance with time.

Abbreviations: AAO, acidic ammonium oxalate • AES, atomic emission spectroscopy • EDAX, energy-dispersive x-ray analysis • FTIR, Fourier transform infrared • ICP, inductively coupled plasma • MAS, magic angle spinning • NCA, noncarbonate alkalinity • SEM, scanning electron microscopy • STW, simulated tank waste • XRD, x-ray diffraction