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a Dep. of Renewable Resources, 442 Earth Sciences Bldg., Univ. of Alberta, Edmonton, AB Canada T6G 2E3
b Dep. of Chemistry, E344 Gunning/Lemieux Chemistry Centre, Univ. of Alberta, Edmonton, AB Canada T6G 2G2
c Natural Resources Canada, Canadian Forest Service, 5320-122 St., Edmonton, AB, Canada T6H 3S5
* Corresponding author (khannam{at}ualberta.ca)
The ability of high-resolution cross-polarization magic-angle spinning 13C nuclear magnetic resonance spectroscopy (CPMAS 13C NMR) to characterize soil organic matter (SOM) has been previously demonstrated, but rarely has this information been directly related to local environmental conditions that affect SOM formation. In this study, CPMAS 13C NMR was used to characterize the forest floor (Oe + Oa horizon) of stands dominated by trembling aspen (Populus tremuloides Michx.) or white spruce [Picea glauca (Moench) Voss] in the boreal mixedwood forest of Alberta, Canada. Aromatic C content was higher and carbonyl C content was lower in the forest floor of spruce stands than in aspen stands. Within stand types, correlation analyses indicated significant relationships between the composition of the forest floor and soil temperature, mass of the Oi horizon, and mass of the moss layer. However, these relationships could not explain observed differences in the chemical composition of the forest floor between stand types. Although forest floor from spruce stands was largely composed of moss, which is low in aromatic C, it had a greater aromatic C content than forest floor from aspen stands, where moss was rare. Furthermore, a lack of significant correlations across stand types suggests that there are different relationships between the chemical and environmental characteristics of forest floor from spruce and aspen stands.
Abbreviations: ALK, alkyl carbon region AROM, aromatic carbon region CARB, carbonyl carbon region CPMAS 13C NMR, cross-polarization magic-angle spinning 13C nuclear magnetic resonance CP, cross-polarization DD, dipolar-dephased EMEND, Ecosystem Management Emulating Natural Disturbance NMR, nuclear magnetic resonance O-ALK, O-alkyl carbon region SOM, soil organic matter
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T. E. Redding, K. D. Hannam, S. A. Quideau, and K. J. Devito Particle Density of Aspen, Spruce, and Pine Forest Floors in Alberta, Canada Soil Sci. Soc. Am. J., August 4, 2005; 69(5): 1503 - 1506. [Abstract] [Full Text] [PDF] |
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