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Agronomy Dep., 313 Sturgis Hall, Louisiana State Univ. Agricultural Center, Baton Rouge, LA. 70803
* Corresponding author (jjwang{at}agctr.lsu.edu).
Plant availability of soil K is controlled by dynamic interactions among its different pools. Misunderstanding of these dynamics leads to mismanagement of soil fertility. This study was conducted to evaluate buffering characteristics of low exchangeable-K soils that showed different sugarcane (Saccharum spp. L.) responses to K amendment. Three silt loams, Crowley (fine, smectitic, hyperthermic Typic Albaqualfs), Dundee (fine-silty, mixed, active, thermic Typic Endoaqualfs), and Norwood (fine-silty, mixed, superactive, hyperthermic Fluventic Eutrudepts), were evaluated by using a modified quantity/intensity (Q/I) approach, which allows partitioning of K changes in the soilsolution system into exchangeable and nonexchangeable pools. Total potential buffering capacity (PBCt) was found to correlate significantly (r = 0.97, P < 0.01) with the buffering capacity due to nonexchangeable K (PBCn) rather with that due to exchangeable K (PBCe). Impact factor (ß), a measure of effect of added K on nonexchangeable K, was inversely correlated with a soil's conversion magnitude (
) of converting added K to exchangeable K (r = 0.95, P < 0.01). Of the three soils, Dundee exhibited much smaller ß values than Crowley and Norwood but the soil converted much of added K to exchangeable K (6065%) throughout its surface and subsurface soils. Both Crowley and Norwood possessed higher PBCt as well as higher PBCn and PBCe than Dundee, but Crowley required relatively lower critical exchangeable K (EKr) and solution K (CKr) levels below which release of nonexchangeable K was initiated. The overall results indicated that the partitioned Q/I approach could be used to explicitly evaluate short-term K dynamics in soilsolution systems. The nonexchangeable K buffering characteristics along with the differences between critical levels (EKr or CKr and EK0 or CK0) have important implications in assessing the likelihood of nonexchangeable K release and could be calibrated for soil fertility management.
Abbreviations: AR, activity ratio CEC, cation-exchange capacity CKi, initial solution K CK0, equilibrium solution K CR, concentration ratio CR0, equilibrium concentration ratio EKo, equilibrium exchangeable K EKr, critical exchangeable K KG, Gapon selectivity coefficient LPBC, linear potential buffering capacity MHA, mobile humic acids PBCe, potential buffering capacity due to exchangeable K PBCn, potential buffering capacity due to nonexchangeable K PBCt, total potential buffering capacity Q/I, quantity/intensity
, slope of linear regression between final exchangeable K (EKf) and change in solution K (
K)
, initial constraint ß, slope of linear regression between change in nonexchangeable K (
Non-Exch K) and initial constraint
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