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Dep. of Plant and Soil Sci., Univ. of Delaware, Newark, DE 19717-1303 USA
mpautler{at}udel.edu
Methods to identify agricultural soils that contribute to nonpoint-source pollution of surface waters by P are of increasing importance, particularly in areas with high animal densities (animal units per hectare of cropland). Our objective was to determine the relationship between agronomic soil test P (STP = Mehlich 1) and other soil P tests proposed to measure the potential for P loss by erosion, runoff, and leaching. We compared STP with soluble P, P in the "fast desorbing pool" (strip P), and soil P saturation for 127 soils (122 from Delaware and five from the Netherlands). Soil test P was significantly correlated with total
, soluble
, strip
, and oxalate-extractable
. Strip P was a better predictor of soluble P than
. The ratio of strip P/Pox (the percentage of reversibly sorbed P in the fast desorbing pool) increased as P sorption capacity, estimated from oxalate-extractable Al and Fe (Alox + Feox), decreased. We also determined the degree of P saturation (DPS) using three methods: Langmuir P sorption isotherms; oxalate extractions of P, Al, and Fe; and STP plus a single-point P sorption index (PSI). Soluble P, STP, and desorbable P increased for DPS values >30%, similar to upper DPS limits in the Netherlands and Belgium. Soils rated agronomically excessive in STP (>50 mg kg-1) had higher ratios of soluble P, strip P, and Pox to total P than those in agronomically optimum or lower categories.
Abbreviations: Alox, Feox, Pox, aluminum, iron, and phosphorus extracted by acid ammonium oxalate DPS, degree of soil P saturation ICPAES, inductively coupled plasma atomic emission spectroscopy OM, organic matter Pw, water soluble P PSCr, remaining P sorption capacity PSCt, total P sorption capacity PSI, single-point P sorption index STP, soil test P UDSTP, University of Delaware Soil Testing Program
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