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a Dep. of Environmental Engineering Sciences, Univ. of Florida, P.O. Box 116450, Gainesville, FL 32611-6450 USA
b School of Civil Engineering, Purdue Univ., West Lafayette, IN 47907-1284 USA
pscr{at}purdue.edu
A series of gaseous miscible displacement experiments were conducted to estimate specific air–water interfacial areas (ai) and water contents in an unsaturated sand column. A straight-chain hydrocarbon (n-decane) was used as the gaseous interfacial tracer and methylene chloride and chloroform were used as the water-partitioning gaseous tracers. A gas chromatographic technique was employed for the tracer experiments conducted at room temperature using nitrogen as the mobile phase and water as the immobile liquid. Tracer experiments covered a water saturation (Sw) range of 1.5 to 56%. The largest ai value (
1500 cm2 cm-3), measured at the lowest Sw (1.5%), was somewhat smaller than the solid surface area (2000 cm2 cm-3) determined using the nitrogen-sorption technique. As Sw increased, ai values decreased exponentially to 80 cm2 cm-3 at Sw of 56%. Within a limited Sw range (0.29 < Sw < 0.55), where both aqueous and gaseous interfacial tracer data were measured, the ai values measured using a gaseous tracer (n-decane) were 2 to 3 times larger than those measured in a previous study using an aqueous interfacial tracer (sodium dodecylbenzene sulfonate [SDBS]). The velocity of the air–water interface was estimated to be between 23 and 36% of the bulk pore-water velocity. The water contents measured using water-partitioning tracers were within ±5% of those based on gravimetric measurements.
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