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Published in Soil Sci Soc Am J 60:1467-1472 (1996)
© 1996 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Release Rates of Phosphorus, Ammonium, and Potassium in Clinoptilolite-Phosphate Rock Systems

E. R. Allen*

P.O. Box 83, Mason City, IL 62664

L. R. Hossner

Dep. of Soil and Crop Sciences, Texas A&M Univ., College Station, TX 77840

D. W. Ming and D. L. Henninger

NASA Johnson Space Center, Houston, TX 77058

*Corresponding author (erallen{at}aol.com).

ABSTRACT

Controlled release of P, NH4, and K can be accomplished in synthetic soils through dissolution and cation-exchange reactions by phosphate rock (PR) and the zeolite mineral, clinoptilolite (Cp). The power-function equation has previously been found to adequately describe transport kinetics of the nutrient release process. Research was conducted to evaluate factors affecting P, NH4, and K release rates in Cp-PR systems. Data was collected using a continuous-flow thin-disk technique. Results were evaluated with the power-function equation. Materials included a Texas Cp and North Carolina and Tennessee PRs. Variables examined included the Cp/PR ratio, the mole fraction of NH4 and K on the Cp, and the type of PR. The power-function model indicated that initial release rates and cumulative nutrient release in Cp-PR mixtures were increased by using a higher Cp-PR ratio and by using a more reactive PR. Nutrient release rates were also affected by changes in the proportion of NH4 and K occupying Cp exchange sites and reflected ion-selectivity characteristics of Cp. The results indicate that Cp and PR may be used to obtain a controlled release of NH4, P, and K in a synthetic soil.

Received for publication April 17, 1995.


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Copyright © 1996 by the Soil Science Society of America.