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Published in Soil Sci Soc Am J 53:201-210 (1989)
© 1989 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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The Stable Isotope Chemistry of Pedogenic Carbonates at Kyle Canyon, Nevada

Ronald G. Amundson* and Harvey E. Doner

Dep. of Plant and Soil Biology, 108 Hilgard Hall, Univ. of Calif., Berkeley, CA 94720

Oliver A. Chadwick

Jet Propulsion Lab., Calif. Inst. of Technology, Pasadena, CA 91109

Janet M. Sowers

U.S. Geological Survey, Menlo Park, CA 94025

* Corresponding author.

ABSTRACT

The C and O isotopic composition and radiometric ages of laminar pedogenic CaCO3 coatings were examined in limestone-derived alluvium along an elevational and climatic transect of the Mojave Desert of Nevada. The {delta}13C of the soil CO2 decreased with increasing elevation and was related to plant density and available soil moisture. Laminar pedogenic carbonate coats which formed on the bottoms of clasts were separated into inner and outer laminae. The {delta}13C of carbonates in the outer laminae decreased with increasing elevation as a result of a decrease in the percentage of detrital carbonate in the sample and a decrease in the {delta}13C of the soil CO2. The {delta}18O of the outer laminae also decreased with elevation and, after correcting for contamination by detrital carbonate, appeared to correspond to changes in the isotopic composition of the precipitation. The {delta}13C of the carbonate in the inner laminae also decreased with increasing elevation; however, carbonate in the inner laminae was much purer than the outer laminae and appeared to be predominantly pedogenic in origin. The {delta}13C of these layers reflects the {delta}13C of soil CO2 and, for most samples, corresponded to expected values for modern carbonate. Based on uncertainties in dating techniques and the estimated range in isotopic composition of pedogenic carbonate, however, it was not possible to determine if some of the inner laminae formed in the latest pluvial period and reflect past pedogenic conditions.


NOTES

Contribution from the Dep. of Plant and Soil Biology, Univ. of Calif, Berkeley.

Received for publication March 14, 1988.





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Copyright © 1989 by the Soil Science Society of America.