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Sorption of -Naphthol: Implications Concerning the Limits of Hydrophobic Sorption¹

ABSTRACT

The effect of soil and sediment properties on sorption of -naphthol was examined. Batch equilibrium sorption isotherms were determined for sorption of -naphthol by soil and sediment samples collected from the Ohio, Missouri, Mississippi, and Illinois rivers and their watersheds. The sorption isotherms were represented by the Freundlich equation. Soil thin-layer chromatography was used in combination with the sorption studies to examine the role of both sorbate and sorbent properties as well as the solute-solvent interaction in determining the degree of hydrophobic or nonpolar sorption.

¹ Contribution from the Dep. of Agronomy & Institute for Environmental Studies, Univ. of Illinois, Urbana. Research support from EPA Contract no. 68-03-2555 and the Illinois Agric. Exp. Stn. are gratefully acknowledged.

² Associate Professors, Assistant Research Biologist, Univ. of Illinois, Urbana, IL 61801, respectively, and Assistant Professor, Univ. of Maryland.

Received for publication August 19, 1979. Accepted for publication September 23, 1980.

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