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Published in Soil Sci Soc Am J 41:537-540 (1977)
© 1977 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Observed and Predicted Rates of Phosphorus Diffusion in Soils of Varying Bulk Density and Water Content1

G. S. Hira and N. T. Singh2

ABSTRACT

The self-diffusion coefficient of phosphorus (D) was measured at bulk densities of 1.25, 1.45, 1.60 and 1.75 g/cm3 and at three levels of soil water content in Choa sandy loam and Haibowal silty clay loam. The tortuosity factor was calculated from the self-diffusion coefficient of 36Cl. Appropriate values of the adsorption isotherm and the tortuosity factor were used to predict P diffusion coefficient in both soils.

The tortuosity factor increased with increase in soil bulk density and increase in water content from 7 to 18% in the Choa soil and 14 to 25% in the Haibowal soil. As bulk density increased from 1.25 to 1.60 g/cm3, the observed diffusion coefficient values averaged over all water contents, increased from 0.05 x 10–10 to 0.31 x 10–10 and 2.13 x 10–10 to 5.07 x 10–10 cm2/sec in Choa and Haibowal soils, respectively. Further increase in bulk density to 1.75 g/cm3 decreased the diffusion coefficient. At high bulk density changes in water content affected the self-diffusion coefficient of P in both soils to a greater extent than at low bulk density. The phosphate ion-soil particle interaction was minimum at a soil bulk density of 1.60 g/cm3.


NOTES

1 Contribution from the Dep. of Soils, Punjab Agric. Univ., Ludhiana, India.

2 Formerly Graduate Student and Senior Soil Physicist, respectively.

Received for publication August 23, 1976. Accepted for publication January 25, 1977.







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Copyright © 1977 by the Soil Science Society of America.