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Published in Soil Sci Soc Am J 35:626-631 (1971)
© 1971 Soil Science Society of America
677 S. Segoe Rd., Madison, WI 53711 USA
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Trace Element Correlation of Volcanic Ash Soils1

G. A. Borchardt and M. E. Harward2

ABSTRACT

Neutron activation of volcanic ash followed by gamma-ray detection with a Ge(Li) semiconductor detector and 4096 multichannel analyzer produced rapid analysis for 19 elements. This was demonstrated to be useful for correlating soil parent materials. The trace element compositions of volcanic glass from C horizons of soils along a 450-km transect in Oregon correlate with known ejecta from Mt. Mazama. Concentration of transition metals in upper horizons relative to C horizons occurred in the order Cr > Co > Fe = Sc. Ratios of Na/Fe and Na/Co increased with depth. The abundances of Hf, Th, and the rare earth elements, as well as Sc/Fe ratios, were relatively constant with depth. Stable elemental ratios unique to Mazama ash aided correlation of weathered soil horizons. Some of the soils of northeastern Oregon may have small amounts of St. Helens ash in upper horizons in addition to the predominant Mazama ash.


NOTES

1 Technical Paper no. 2971, Oregon Agr. Exp. Sta., Corvallis. Financial support through Atomic Energy Commission contract AT (45-1)-2062 is gratefully acknowledged. Presented before Div. S-5 and S-9, Soil Science Society of America, Nov. 13, 1969, Detroit, Mich.

2 NRC Postdoctoral Research Associate, Nuclear Science Building, USGS, Denver Federal Center, Denver, Colo. 80225 (formerly Graduate Research Assistant in Soils, Oregon State Univ.); and Professor, Department of Soils, Oregon State Univ., respectively.

Received for publication November 24, 1970. Accepted for publication March 19, 1971.







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