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ABSTRACT
The selectivity coefficient, the ratio of Sr to Ca as exchangeable cations divided by the ratio of Sr to Ca in solution, was found to vary from 0.61 to 1.51 on 63 Indiana soils. Soil factors influencing the variation in kc values were studied on selected soils where kc was determined after equilibration of the soil with an 0.1N chloride solution of Ca and Sr having a Ca/Sr molar ratio of approximately 190:1.
Organic matter was negatively correlated with the kc value (r = 0.83). Removal of the organic matter with H2O2 on nine soils increased the kc value. The magnitude of the increase was correlated with the percent organic matter in the soil (r = 0.89). The organic fraction of the soil adsorbed Ca preferentially to Sr. The inorganic fraction in most instances adsorbed Sr preferentially.
1 Journal Paper no. 3093, Purdue University, Agr. Exp. Sta., Lafayette, Ind. Contribution from the Department of Agronomy. Presented before Div. S-2, Soil Science Society of America, Aug. 24, 1966, at Sillwater, Okla. This research was supported in part by the U.S. Atomic Energy Commission under Contract AT(11-1)-1495.
2 Research Associates and Professor of Agronomy, respectively, Dr. Khasawneh is now Research Chemist, Soils & Fertilizer Research Branch, TVA, Muscle Shoals, Ala.
Received for publication August 28, 1967. Accepted for publication September 11, 1967.
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