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ABSTRACT
The evolution of nitrogen gases from four soils was studied by total soil nitrogen analysis, the mass spectrometer with N15-labeled nitrogen carriers, and with infrared spectroscopy. The type and amount of nitrogen gas evolved was influenced by a number of factors. Soil type was important in that the Nicollet and Fargo soils resulted in the evolution of more N2 and N2O than did the Fayette and Laredo soils. Soil properties had little effect on the total N2 evolved from NH4NO3, but greater differences occurred from soils treated with HNO3. The type of nitrogen carrier influenced the nature of the gaseous nitrogen released. NH4NO3 treatment favored N2O evolution and HNO3 treatment favored N2. Only small amounts of N2 and N2O were evolved from soils treated with NH4Cl or urea. Nitrogen applied at 1080 pounds per acre always resulted in larger losess of N2O and N2 than that applied at 360 pounds per acre. However, in both the Nicollet and Fargo soils at water saturation, the percentage of applied nitrogen that was lost was about the same at both low and high rates of treatment. Substantial gaseous losses of applied fertilizer occurred mainly when water-saturated conditions prevailed. Small losses did occur from soils at field moisture capacity. N2O evolution was influenced by the ammonium to nitrate ratio of the nitrogen treatment.
1 Paper No. 4439 Scientific Journal Series, Minnesota Agr. Exp. Sta., University of Minnesota, St. Paul. Presented before Div. II, Soil Science Society of America, Nov. 17, 1959, at Cincinnati, Ohio.
2 Formerly Research Assistant, Department of Soils, present address Dow Chemical Co., Washington, D. C.; Professor, Department of Soils; Associate Professor, jointly Department of Soils and Department of Bacteriology, respectively.
Received for publication July 22, 1960. Accepted for publication September 30, 1960.
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