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Fig. 1. (a) Spin-lattice relaxation times (T1) of {alpha}, ß, and {gamma} deuterium of d5–pyridine in water as a function of pH. (b) T1 of {alpha} deuterium of d5–pyridine in water, 0.001 M benzoic acid (C6H5COOH) and 0.001 M phenol (C6H5OH) solutions as a function of pH, and modeled T1 in water. For both (a) and (b), the measurement error is generally <1% and approximately the same size as the symbols used).