Fig. 7. Measured and optimized a (a) short-term (24 h adsorption and 24 h desorption) and (b) longer-term (168 h adsorption and 168 h desorption step) adsorption-desorption isotherms using the TCOR model (solid lines). The dotted line is the true equilibrium isotherm based on the optimized model parameters. (c) Predicting longer-term adsorption-desorption isotherms using model parameters optimized on short-term data (Table 4, solid lines). Dotted lines represent true equilibrium based on short-term parameters.